2020-2021 / CHIM9284-2

Analytical chemistry I - Chemical analysis methods , Theory

Duration

20h Th

Number of credits

 Master of Science (MSc) in Geological and Mining Engineering2 crédits 
 Master of Science (MSc) in Geological and Mining Engineering (Co-diplomation avec l'Université polytechnique de Madrid)2 crédits 
 Bachelor in geology2 crédits 

Lecturer

Gauthier Eppe

Language(s) of instruction

French language

Organisation and examination

Teaching in the first semester, review in January

Schedule

Schedule online

Units courses prerequisite and corequisite

Prerequisite or corequisite units are presented within each program

Learning unit contents

The balanced reactions (acid-bases, redox, complexation, precipitation) are treated in terms of exchange of particles between donors and acceptors, thus unifying the concepts used in the study of the various reactions in aqueous solution. The next step consists in establishing a relationship between the variations of the conditional constants (acidity constants, formation constants of complex, normal potentials, exchange and partition constants) and the conditions of the medium (pH, ionic strength, complexing agent). These concepts being acquired, the implementation and the quantitative application of these various reactions with the purpose of analysis (titrimetry and gravimetry, primarily) are considered while insisting on accuracy which one should expect. 

Learning outcomes of the learning unit

To understand, interpret and apply the various reaction steps of an analysis protocol in order to obtain the best performances in terms of accuracy and precision. They are the major objectives of the course. This implies a good knowledge of the chemical reactions which it implements.

Prerequisite knowledge and skills

The course of general chemistry in 1st bachelor

Planned learning activities and teaching methods

See below

Mode of delivery (face to face, distance learning, hybrid learning)

The course takes place every Friday morning from 8:15 to 10:15 am. The lessons  are illustrated by several experimental demonstrations adn exercices. The rehearsals are given after the theoritical course  from 10:30 to 12:30 or during the afternoon by A. Verdin (assistant).
These rehearsals illustrate the course and contribute to its understanding thanks to a series of problems and exercises on the various chapters, while insisting particularly on acid-base and complexometric titrations, Redox and Pourbaix diagrams which are of primary importance for geologists. 
  The sudents are invited to work by group max 3 to 4 on series of exercices proposed and posted on e-campus. The students are free to prepare in advance the rehearsals The corrections are done at together at the black board. 

Organisational adjustments related to the current health context

Recommended or required readings

The course notes and the exercices book are available at the Presses Universitaires 
A copy of the powerpoint slides are also available.
As supplementary information, the consultation of the following works is recommended: - ETUDE ANALYTIQUE DES REACTIONS CHIMIQUES DANS L'EAU by J.Y. GAL (TEC et DOC-LAVOISIER, Paris 1989) - ANALYTICAL CHEMISTRY by D.A.SKOOG, D.M. WEST and F.J HOLLER. 3rd Edition (2015)

Assessment methods and criteria

Below you will find information on the evaluation methods planned for in-person and remote exams as well as those planned for hybrid sessions. Depending on how the health crisis evolves, the chosen method will be communicated to you no later than one month before the start of the exam session.

6 written testing are planned during the TD. The test is  related on the subject developed during the previous course. 30 minutes are foreseen for the test at the beginning of the TD. The 4 highest notes out of the 6 are kept to calculate the mean and might lead to a bonus. A participation rate lower than 4 tests, does not give right to any bonus.
The distribution of the bonus for the exam is the following :
 
Criteria (mean value from 4 best tests)
  Mean < 12/20                Bonus +0
12<=  Mean < 14/20.     Bonus +1
14<=Mean < 16/20        Bonus +2
16<= Mean < 18/20       Bonus +3
18<= Mean < 20/20       Bonus +4
 
En présentiel
L'évaluation consiste en un examen écrit de 4h en janvier sur l'ensemble de la matière. L'examen est principalement basé sur la résolution d'exercices et d'applications directes des principes vus au cours.
 
Modalité d'évaluation en distanciel :
L'évaluation consiste en un examen écrit de 4h en janvier sur l'ensemble de la matière. L'examen se constitue de 4 questions ouvertes sur les principaux chapitres du cours (réactions acide-base, réactions de complexation, réactions d'oxydoréduction). L'énoncé de l'examen sera disponible via eCampus pour la durée de l'examen uniquement et les résolutions devront être envoyées par les étudiants via photo/scanner dans un délai prédéfini après la fin de l'examen. Un non-respect de ce délai peut entraîner une annulation de l'examen.
Une surveillance via une plateforme vidéo (Blackboard, lifesize, autre) sera mise en place durant toute la durée de l'examen. Durant cette période, la caméra ainsi que le micro des étudiants devront rester allumés.
 

Work placement(s)

Organizational remarks

Contacts

Pr. Gauthier Eppe Institut de Chimie, Bat B6c, Local 1/9A Tel. +32-4-366.3422 e-mail. g.eppe@uliege.be

Assistant A. Verdin
e-mail: alexandre.verdin@uliege.be