Duration
Theory : 26h Th
Practice : 26h QA Sess.
Number of credits
| Bachelor in chemistry | 3 crédits |
Lecturer
Theory : Gauthier Eppe
Practice : Gauthier Eppe
Coordinator
Language(s) of instruction
French language
Organisation and examination
Teaching in the first semester, review in January
Schedule
Units courses prerequisite and corequisite
Prerequisite or corequisite units are presented within each program
Learning unit contents
The balanced reactions (acid-bases, redox, complexation, precipitation) are treated in terms of exchange of particles between donors and acceptors, thus unifying the concepts used in the study of the various reactions in aqueous solution. The next step consists in establishing a relationship between the variations of the conditional constants (acidity constants, formation constants of complex, normal potentials, exchange and partition constants) and the conditions of the medium (pH, ionic strength, complexing agent). These concepts being acquired, the implementation and the quantitative application of these various reactions with the purpose of analysis (titrimetry and gravimetry, primarily) are considered while insisting on accuracy which one should expect.
Theory
The balanced reactions (acid-bases, redox, complexation, precipitation) are treated in terms of exchange of particles between donors and acceptors, thus unifying the concepts used in the study of the various reactions in aqueous solution. The next step consists in establishing a relationship between the variations of the conditional constants (acidity constants, formation constants of complex, normal potentials, exchange and partition constants) and the conditions of the medium (pH, ionic strength, complexing agent). These concepts being acquired, the implementation and the quantitative application of these various reactions with the purpose of analysis (titrimetry and gravimetry, primarily) are considered while insisting on accuracy which one should expect.
Learning outcomes of the learning unit
To understand, interpret and apply the various reaction steps of an analysis protocol in order to obtain the best performances in terms of accuracy and precision. They are the major objectives of the course. This implies a perfect knowledge of the chemical reactions involved in solution, the notions of multiple equilibria and the influence of experimental parameters on the evolution of these reaction equilibria in solution.
Theory
To understand, interpret and apply the various reaction steps of an analysis protocol in order to obtain the best performances in terms of accuracy and precision. They are the major objectives of the course. This implies a good knowledge of the chemical reactions which it implements.
This course contributes to the learning outcomes I.1, I.2, II.1, II.3, III.1, III.2, IV.2 of the MSc in chemical engineering.
This course contributes to the learning outcomes I.1, I.2, II.1, II.3, III.1, III.2, IV.2, IV.3 of the MSc in geological and mining engineering.
Prerequisite knowledge and skills
The course of general chemistry in 1st bachelor
Theory
The course of general chemistry in 1st bachelor
Planned learning activities and teaching methods
See below
The course takes place every Friday morning from 8:15 to 10:15 am. The lessons are illustrated by several experimental demonstrations adn exercices. The rehearsals are given after the theoritical course by Hugo Muller (assistant) at the same place from 10:30 to 12:30.
These rehearsals illustrate the course and contribute to its understanding thanks to a series of problems and exercises on the various chapters, while insisting particularly on acid-base and complexometric titrations, Redox and Pourbaix diagrams.
The sudents are invited to work by group max 3 to 4 on series of exercices proposed and posted on e-campus. The students are free to prepare in advance the rehearsals The corrections are done at together at the black board.
Theory
See below
Practice
The course takes place every Friday morning from 8:15 to 10:15 am. The lessons are illustrated by several experimental demonstrations adn exercices. The rehearsals are given after the theoritical course by G. Eppe and H. Muller (assistant) at the same place from 10:30 to 12:30.
These rehearsals illustrate the course and contribute to its understanding thanks to a series of problems and exercises on the various chapters, while insisting particularly on acid-base and complexometric titrations, Redox and Pourbaix diagrams which are of primary importance for geologists.
The sudents are invited to work by group max 3 to 4 on series of exercices proposed and posted on e-campus. The students are free to prepare in advance the rehearsals The corrections are done at together at the black board.
Mode of delivery (face to face, distance learning, hybrid learning)
Face-to-face course
Additional information:
Face-to-face course
Additional information:
The course takes place every Friday morning from 8:15 to 10:15 am. The lessons are illustrated by several experimental demonstrations adn exercices. The rehearsals are given after the theoritical course by H. Muller (assistant) at the same place from 10:30 to 12:30.
These rehearsals illustrate the course and contribute to its understanding thanks to a series of problems and exercises on the various chapters, while insisting particularly on acid-base and complexometric titrations, Redox and Pourbaix diagrams which are of primary importance for geologists.
The sudents are invited to work by group max 3 to 4 on series of exercices proposed and posted on e-campus. The students are free to prepare in advance the rehearsals The corrections are done at together at the black board.
Theory
Face-to-face course
Additional information:
The course takes place every Friday morning from 8:15 to 10:15 am. The lessons are illustrated by several experimental demonstrations adn exercices. The rehearsals are given after the theoritical course from 10:30 to 12:30 or during the afternoon by Hugo Muller (assistant).
These rehearsals illustrate the course and contribute to its understanding thanks to a series of problems and exercises on the various chapters, while insisting particularly on acid-base and complexometric titrations, Redox and Pourbaix diagrams which are of primary importance for geologists.
The sudents are invited to work by group max 3 to 4 on series of exercices proposed and posted on e-campus. The students are free to prepare in advance the rehearsals The corrections are done at together at the black board.
Recommended or required readings
The course notes and the exercices book are available at the Presses Universitaires
A copy of the powerpoint slides are also available.
As supplementary information, the consultation of the following works is recommended:
- ETUDE ANALYTIQUE DES REACTIONS CHIMIQUES DANS L'EAU by J.Y. GAL (TEC et DOC-LAVOISIER, Paris 1989)
- ANALYTICAL CHEMISTRY by D.A.SKOOG, D.M. WEST and F.J HOLLER. 3rd Edition (2015)
Theory
The course notes and the exercices book are available at the Presses Universitaires
Chimie Analytique I: Méthodes chimiques d'analyse 2021-2022, G. Eppe
A copy of the powerpoint slides are also available.
As supplementary information, the consultation of the following works is recommended:
- ETUDE ANALYTIQUE DES REACTIONS CHIMIQUES DANS L'EAU by J.Y. GAL (TEC et DOC-LAVOISIER, Paris 1989)
- ANALYTICAL CHEMISTRY by D.A.SKOOG, D.M. WEST and F.J HOLLER. 3rd Edition (2015)
Assessment methods and criteria
Exam(s) in session
Any session
- In-person
written exam ( open-ended questions )
Continuous assessment
Additional information:
Exam(s) in session
Any session
- In-person
written exam ( open-ended questions )
Continuous assessment
Out-of-session test(s)
Additional information:
9 written testing out of 10 are planned during the TD. The test is related on the subject developed during the previous course. 30 minutes are foreseen for the test at the beginning of the TD. The 6 highest notes out of the 9 are kept to calculate the mean and might lead to a bonus. A participation rate lower than 6 tests, does not give right to any bonus.
The distribution of the bonus for the exam is the following :
Criteria (mean value from 6 best tests)
Mean < 12/20 Bonus +0
12<= Mean < 14/20. Bonus +1
14<=Mean < 16/20 Bonus +2
16<= Mean < 18/20 Bonus +3
18<= Mean < 20/20 Bonus +4
Examen in person, written exam :
The Analytical Chemistry I exam: The exam is a closed book exam consisting of open-ended exercise questions.
The exam consists of 3 to 4 open-ended exercise questions that may cover all 4 chapters of the course. Note that for chemical engineers, one of the open questions will be dedicated on chromatographic separation methods.
Theory
Exam(s) in session
Any session
- In-person
written exam ( open-ended questions )
Continuous assessment
Out-of-session test(s)
Additional information:
6 written testing are planned during the TD. The test is related on the subject developed during the previous course. 30 minutes are foreseen for the test at the beginning of the TD. The 4 highest notes out of the 6 are kept to calculate the mean and might lead to a bonus. A participation rate lower than 4 tests, does not give right to any bonus.
The distribution of the bonus for the exam is the following :
Criteria (mean value from 4 best tests)
Mean < 12/20 Bonus +0
12<= Mean < 14/20. Bonus +1
14<=Mean < 16/20 Bonus +2
16<= Mean < 18/20 Bonus +3
18<= Mean < 20/20 Bonus +4
In-person, written exam
The evaluation consists of a written exam of maximum 4 hours in January on the whole subject. The exam is mainly based on solving exercises and direct applications of the principles seen in the course.
Practice
9 written testing out of 10 are planned during the TD. The test is related on the subject developed during the previous course. 30 minutes are foreseen for the test at the beginning of the TD. The 6 highest notes out of the 9 are kept to calculate the mean and might lead to a bonus. A participation rate lower than 6 tests, does not give right to any bonus.
The distribution of the bonus for the exam is the following :
Criteria (mean value from 6 best tests)
Mean < 12/20 Bonus +0
12<= Mean < 14/20. Bonus +1
14<=Mean < 16/20 Bonus +2
16<= Mean < 18/20 Bonus +3
18<= Mean < 20/20 Bonus +4
The evaluation consists in a 4h written examination in January covering all topics mainly focused on exercises and direct applications of the principle seen during the lectures.
There is second session (August/September) if the note is strictly lower than 10/20.
Work placement(s)
Organisational remarks and main changes to the course
Contacts
Pr. Gauthier Eppe
Institut de Chimie, Bat B6c, Local 1/9A
Tel. +32-4-366.3422
e-mail. g.eppe@uliege.be
Assistant (Bloc 2 in chemical sciences et Master 1 chemical engineering) :Hugo Muller: hugo.muller@uliege.be
Assistante (Bloc 3 in geological sciences et Master 1 in geological and mine engineering): Aurore Schneiders: aschneiders@uliege.be
Theory
Pr. Gauthier Eppe
Institut de Chimie, Bat B6c, Local 1/9A
Tel. +32-4-366.3422
e-mail. g.eppe@uliege.be
Assistant (Bloc 2 in chemical sciences et Master 1 chemical engineering) :Hugo Muller: hugo.muller@uliege.be
Assistante (Bloc 3 in geological sciences et Master 1 in geological and mine engineering): Aurore Schneiders: aschneiders@uliege.be
Practice
Assistant (Bloc 2 in chemical sciences et Master 1 chemical engineering) :Hugo Muller: hugo.muller@uliege.be
Assistante (Bloc 3 in geological sciences et Master 1 in geological and mine engineering): Aurore Schneiders: aschneiders@uliege.be