University of Liege | Version française
Academic year 2014-2015Value date : 12/05/2015
CHIM0713-1  General and mineral chemistry preparatory to pharmaceutical sciences, Part II

Duration :  30h Th, 34h Pr, 26h QA Sess.
Number of credits :  
Bachelier en sciences pharmaceutiques6
Lecturer :  Edwin De Pauw
Language(s) of instruction :  
French language
Organisation and examination :  
Teaching in the second semester
Course contents :  
The general chemistry course devotes significant time to the experimental approach to chemistry. We are convinced that students will be more receptive to chemistry when it is described in a practical manner, by focussing on its resulting application. The programme proposed is intentionally limited to basic concepts to ensure that students acquire a solid foundation in the subject matter.
Chapter 1: Atom and molecules
1.1       The periodic table of the elements
1.2       The electronic structure of atoms
1.3       Atomic orbitals
1.4       Hybrid atomics orbitals
1.5       the chemical bond, qualitative description
1.6       Introduction to the description of the chemical bond
1.7       molecular orbitals
1.8       Diatomic molecues
1.9      Polyatomic molecules
1.10    The 3D structure of molecules
1.11    The Gillespie rules
Chapter 2 : Basic concepts of thermodynamics
2.1       Introduction to thermodynamics
2.2       The system
2.3       State functions and variables
2.4       The equilibrium
2.5       Transformations of a system
Chapter 3 : Energy
3.1       Internal energy and the first principle
3.2       Echange d'énergie entre un système et son environnement
3.3       State functions
3.4       Reversibility
3.5       Heat exchange
3.6       Internal energy, enthalpy
3.7       Thermochemistry
Chapter 4 : Entropy, the second and third principles
4.1       The second law
4.2       Macroscopic definition of entropy
4.3      Entropy and the second law
4.4       Entropy and temperature
4.5       Zero K entropy
4.6       Entropy changes and the chemical reaction
Chapter 5 : The chemical potential
  5.1       Spontaneous reaction criterium
5.2       Phase diagrams, pure compounds
5.3       Molar fractions
5.4       Chemical potential and concentrations
5.5       Colligative properties
Chapter 6 : lreactions in solution
6.1       Acid and bases
6.2       Acid-base equilibria
6.3       Soubility and precipitation
6.4       Complexation
6.5       Combind equilibria
 
Chapter 7: Chemical kinetics, an introduction
7.1       Writing a rate of reaction
7.2       Reaction order
7.3       The rate constant
7.4       Rate constant and temperature
7.5       The transition state
7.6       The complex reaction kinetics
7.7       The polymerisation reaction
7.8       Adsorption, desorption
Chapter 8 Introduction to electrochemistry, complements :
- Conductivity
- Ions miration law
- Electrolytes
Learning outcomes of the course :  
General chemistry teaching during the second period of the year aims to give students in Chemisty and in Geology the basic theoretical and practical concepts in molecular chemistry, thermodynamics, kinetics, and solution chemistry (reactivity). These concepts are necessary in order to understand the phenomena studied in later parts of the curriculum. Theoretical classes, practical work and tutorials allow students to learn the methods and basic techniques of solution chemistry while familiarising them with the formulae of the chemical products and understanding their evolution by change of phase or reaction. A special focus will be given to the chemical equilibrium conditions.
Prerequisites and co-requisites/ Recommended optional programme components :  
For the entire course, the student is assumed to have very basic understanding of chemistry and in particular, to have knowledge of the basics of atomic and molecular theory as well as the elemental properties of the main types of chemical compounds (oxides, acids, bases and salts) and their principal reactions. These concepts will, however, be revised early on in the course. This course also makes use of a range of simple physical and mathematical tools.
Planned learning activities and teaching methods :  
Four practical lab sessions are scheduled for the academic year. They are compulsory and are graded. They illustrate significant concepts of reactivity in solution. A calendar will be distributed to students at the beginning of the academic year. Students are required to wear lab coats.
Mode of delivery (face-to-face ; distance-learning) :  
Each student will receive a personalised programme (log book) at the start of the year summarising all the information relating to the organisation of chemistry teaching (theory classes, practical sessions, revision, tutorials, tests). The theory classes will take place on Tuesdays and Wednesdays between 0830 and 1000.<br /><br /> n.a.
Recommended or required readings :  
The course notes are made up of a photocopy called "Chimie Générale". This is accompanied by an interactive CD-ROM on learning chemistry. Lab notes and exercises, recapitulative tables and a formulaic table. Students can use the formulaic table during all the exams and tests.<br /><br /> n.a.
Assessment methods and criteria :  
Assessment is carried out through three exempting written tests (problem-based questions) and a theory examination covering all the material from the first quarter and an exam for non-exempted students. The overall grade is an average of the results obtained during the exams (4/5) and the practical work sessions (1/5) during the first quarter.
Work placement(s) :  
Organizational remarks :  
Lecture notes and illustrations will be available online (myulg) after each lesson.
Contacts :  
Prof. Edwin De Pauw
E.DePauw@ulg.ac.be



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