University of Liege | Version française
Study programmes 2011-2012Last update : 14/06/2012
CHIM0012-3  Chemical Kinetics

Duration :  20h Th, 15h Pr
Number of credits :  
Bachelor in engineering sciences, civil engineer orientation (Bachelor in engineering sciences, civil engineer orientation), 2nd yearToute l'année3
Lecturer :  Jean‑Paul Pirard
Language(s) of instruction :  
French language
Course contents :  
Course in Chemical Kinetics : Stoichiometry. The extent of reaction. Definition of an elementary step. Transition-state theory. The rate of an elementary step. Thermodynamic formulation of rates. The collision theory and the equation of Arrhenius. Single reactions : open and closed sequences. The steady-state approximation. Kinetic treatment of catalytic sequences. Kinetic treatment of chain reactions. Principle of microscopic reversibility. Kinetics of polymerisation. The rate-determining step. Shift in rate-determining step. Rate-determining active centers. Ambiguity of simplified kinetics.
Learning outcomes of the course :  
Notions of chemical kinetics necessary to calculate chemical reactors and to study heterogeneous catalysis.
Prerequisites and co-requisites/ Recommended optional programme components :  
Good knowledge of the basic concepts of the courses of general chemistry.
Planned learning activities and teaching methods :  
Analysis of an article of chemical kinetics recently published in a scientific journal. This work is carried out by groups of two students, is presented in a written report by each student and is the subject of an oral interrogation.
Mode of delivery (face-to-face ; distance-learning) :  
First semester
Recommended or required readings :  
Written notes available for the whole course at the first lesson. These notes are accompanied with a booklet of exercises.
Assessment methods and criteria :  
Oral examination on theory and written examination on exercises.
Oral interrogation on scientif article of chemical kinetics analysed during worshops.
Contacts :  
Professeur Jean-Paul PIRARD
Department of Applied Chemistry
Chemical Engineering Laboratory
University of Liège
Institut de Chimie - B6a
4000 Liège, Belgium
Tel. : 32-(0)4-366 35 58
Fax : 32-(0)4-366 35 45
e-mail : Jean-Paul.Pirard@ulg.ac.be


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