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| CHIM0237-1 | Analytical chemistry in nonaqueous solvents | |||||
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| Duration : | 15h Th | |||||
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| Holder(s) : | Bernard Gilbert | |||||
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| Course contents : | First part: General considerations on non-aqueous solvents: The solvent and the aqueous solution - types of solvents - the process of solvation - in molecular media dissociating and not dissociating - in ionic media Thermodynamic aspects of solvation - definition of the standard state - measurement of a coefficient of activity in non-aqueous media - correlation of the analytical properties while passing from one solvent to the other: - transfer properties Second part: Analytical aspects: Acid-base concepts with protons exchange - in dissociating media - in non dissociating media - in ionic media. Variation of a property following the transfer of a S1 solvent towards anotherS2 solvent. Ions Exchange with participation of the solvent. Oxydoreduction in non-aqueous media | |||||
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| Course objective : | The goal of the course is not to give details on the applications of non-aqueous solvents but to present the fundamental concepts which allow to evaluate a solvent for an given analytical reaction, on the basis of qualitative and quantitative considerations. The emphasis is on the general conclusions of these concepts and especially, on their limitations. | |||||
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| Prerequisites : | Good knowledge of the basic concepts of electrochemistry and thermodynamics presented in previous years | |||||
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| Organization : | Theoretical course, on the 1st or 2d semester Duration: 15 hours | |||||
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| Written notes : | Course notes and transparencies were written, in English, and are available | |||||
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| Assessment : | The evaluation includes: a general examination in May-June (one hour of written preparation followed by an oral defense) | |||||
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| Contacts : | B GILBERT, Professor Analytical Chemistry and Electrochemistry. Institute of Chemistry (B6) (1st floor) Tel.: 04/366.33.37 (secretary), 04/366.35.67 (office) - E-mail: b.gilbert@ulg.ac.be | |||||
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ULg : Students and Studies Administration - Academic Affairs
Contact : Monique Marcourt, direction A.E.E.
Date of data : 18/05/2007
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