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| CHIM0206-1 | General chemistry II | |||||
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| Duration : | 45h Th, 30h Pr, 30h QA Sess. | |||||
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| Holder(s) : | Edwin De Pauw | |||||
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| Course contents : | 1. Classical Thermodynamics, including te microscopic description Degrees of freedom Molar heat components The Boltzmann law The chemical potential and the equilibrium 2. Transformation at equilibrium The moderation theorem The variance Phase diagrams of pure compounds Binary and ternary mixtures (distillation, eutectic, peritectic, solubility...) Colligative properties 3. Introduction to Irreversible phenomena Heat transport Diffusion Viscosity 4. Electrochemistry Potentiometry Redox reactions Thermodynamics of electrode reactions (Nernst equation) Electrode potential Debye-Huckel law of electrolytes Classification of the electrodes Conductometry Electric conduction in solution (ohm law in solution) Independant migration of ions Strong and Weak electrolytes Hittorf numbers Batteries Electrochemical titration methods 5. Surface thermodynamics Surface tension Pressure at interfaces Capillarity Vapor pressure of droplets Adsorption-desorption Insoluble films 6. Group theory | |||||
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| Course objective : | In the second course on general chemistry ( General Chemistry II), the topics introduced during the first course (General Chemistry I) are described in details to open the way to the generalisation of physico-chemical concepts and their applications. The topics of the course are grouped in 5 chapters. Chapter 1 is intended to give solid basis in classical thermodynamics starting from an extended introduction to its microscopic description. These concepts are applied to equilibrium situations in chapter 2. Thermodynamic and kinectic aspects of electrochemistry are presented in chapter 3. Systems, in irreversible evolution close to equilibrium are described in chapter 4. Practical aspects of surface physical chemistry are the core of chapter 5. A chapter on group theory is organised Dr. Raty, research associate at the FNRS. | |||||
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| Prerequisites : | Good knowledge of general chemistry (first year) | |||||
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| Organization : | 45 hours theory, 30 hours problems solving, 30 hours practical work (laboratory) upon request revisions | |||||
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| Written notes : | Chimie générale II, , E . De Pauw Physical Chemistry, P. Atkins, | |||||
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| Assessment : | the final evaluation concerns all the parts of the course (theory, problems, laboratory work) | |||||
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| Contacts : | Enseignant : De Pauw Edwin e.depauw@ulg.ac.be tél: 3663415 Secrétariat : Danielle Salvé d.salve@ulg.ac.be tél: 3663414 Assistant Responsable : Pierre Colson Pierre.Colson@ulg.ac.be tél: 3663435 | |||||
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ULg : Students and Studies Administration - Academic Affairs
Contact : Monique Marcourt, direction A.E.E.
Date of data : 27/02/2006
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