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| CHIM0084-1 | Physical chemistry I | |||||
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| Duration : | 30h Th, 15h Mon. WS, 20h Pr. | |||||
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| Holder(s) : | Edwin De Pauw | |||||
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| Course contents : | 1. Classical Thermodynamics, including te microscopic description Degrees of freedom Molar heat components The Boltzmann law The chemical potential and the equilibrium 2. Transformation at equilibrium The moderation theorem The variance Phase diagrams of pure compounds Binary and ternary mixtures (distillation, eutectic, peritectic, solubility...) Colligative properties 3. Electrochemistry Potentiometry Redox reactions Thermodynamics of electrode reactions (Nernst equation) Electrode potential Debye-Huckel law of electrolytes Classification of the electrodes Conductometry Electric conduction in solution (ohm law in solution) Independant migration of ions Strong and Weak electrolytes Hittorf numbers Batteries Electrochemical titration methods 4. Introduction to spectroscopy | |||||
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| Course objective : | In the second course on general chemistry ( General Chemistry II), the topics introduced during the first course (General Chemistry I) are described in details to open the way to the generalisation of physico-chemical concepts and their applications. The topics of the course are grouped in 5 chapters. Chapter 1 is intended to give solid basis in classical thermodynamics starting from an extended introduction to its microscopic description. These concepts are applied to equilibrium situations in chapter 2. Thermodynamic and kinectic aspects of electrochemistry are presented in chapter 3. 10 hours are devoted to thermodynamic under extreme conditions and to an introduction to spectroscopy (organised Prof. B. Leyh). | |||||
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| Prerequisites : | Good knowledge of general chemistry (fisrt year) | |||||
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| Organization : | 30 hours of theory 15 hours of probelms solving 20 hours of practical work (laboratory) upon request revisions at the end of the program | |||||
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| Written notes : | Chimie générale II, , E . De Pauw Physical Chemistry, P. Atkins, | |||||
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| Assessment : | The final evaluation concerns all the parts of the course (theory, problems, laboratory) | |||||
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| Contacts : | Enseignant : De Pauw Edwin e.depauw@ulg.ac.be tél: 3663415 Secrétariat : Danielle Salvé d.salve@ulg.ac.be tél: 3663414 Assistant Responsable : Pierre Colson Pierre.Colson@ulg.ac.be tél: 3663435 | |||||
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ULg : Students and Studies Administration - Academic Affairs
Contact : Monique Marcourt, direction A.E.E.
Date of data : 27/02/2006
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